The comparative cost of learning would be a fair amount higher with the Nikonos. Think about the cost of the films and then developing them. From having had a quick look on the net seems about $7 per film then presume developing cost say $5 though it is probably more. For me, when i first got my housing for the 5D MkII i shot around 10,000 shots in the first 3 months (i dive 2-4 times a day, pretty much every day). ok, so that is a lot of shots but i just could never have taken the scope of shots and learnt nearly as fast. I had been shooting with a point and shoot for a few years before so i was not totally new to shooting underwater but when moving to the larger dSLR it almost felt like starting again. Simple maths.. if you work it out to be $12 per 36 shots.. it works out to be a bit below $3500 to have taken the same number of shots with the nikon.
If you really want to shoot with the Nikonos i personally think that by far the best route would be to get a housing for you 5D, and learn and practice with that. Sure take a few with the Nik at while your at it, you already have it so why not... It will just take you so much longer to gain the same experience just using the nik, then when you are have the best of both worlds and can come back and say which you think reigns! But hey, if you don't really care about having lots and lots of incredibly frustrating dives with a lot of unusable shots costing you a considerable amount of cash to take.. then hell, just stick with the nikonos. Still reckon it will end up cheaper paying for new housing a strobes for your canon.
As for it is the best wide angle lens for UW.. from the nikon range the 13mm f/5.6 AI-s def kicks it but if you have got that sort of money to spend (saw one sell for £25,000) then hell, all of this is just plain academic as the chances are you would have all the stuff you wanted!!
